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Novak Djokovic, Stanislas Wawrinka, David Ferrer and Li Na are all due on court today.
World no.2 Djokovic will face the experienced Radek Stepanek on Centre court following the opening match between Chanelle Scheepers and Sara Errani.
Wawrinka faces qualifier Piere Riba from Spain in his first-round showdown in the second game of the day in the main arena.
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Milos Raonic follows against wild card Simeon Bolelli before Na closes play on Centre court in her game against qualifier Casey Dellacqua.
Ferrer versus Mikhail Kukushkin is the final pairing of the day on the Grandstand court.
Wild card and Italian hopeful Camila Giorgi plays no.9 seed Dominika Cibulkova in the first game on the Pietrangeli show court.